Naik, Ann and Meina, Liu and Zabel, Manfred and Reiser, Oliver (2010) Efficient Aerobic Wacker Oxidation of Styrenes Using Palladium Bis(isonitrile) Catalysts. CHEMISTRY-A EUROPEAN JOURNAL, 16 (5). pp. 1624-1628. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
The palladium-catalyzed aerobic oxidation of alkenes and especially styrenes (Wacker oxidation) by using chiral pseudo C-2-symmetrical bis(isonitrile) ligands in the absence of further cocatalysts gives rise to methyl ketones in a highly chemoselective manner. The palladium bis(isonitrile) catalyst was characterized by NMR spectroscopy and X-ray structure analysis, revealing a dissymmetric coordination of palladium by the two isonitrile moieties
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CARBON DOUBLE-BONDS; MOLYBDENUM ISONITRILE COMPLEXES; TERMINAL OLEFINS; BIS-SILYLATION; LIGAND; DISCOVERY; isonitriles; methyl ketones; palladium; styrenes; Wacker oxidation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 12 Aug 2020 09:55 |
| Last Modified: | 12 Aug 2020 09:55 |
| URI: | https://pred.uni-regensburg.de/id/eprint/25393 |
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