Kunkely, Horst and Vogler, Arnd (2010) Photoreduction of carbonate in a copper(I) complex. INORGANIC CHEMISTRY COMMUNICATIONS, 13 (1). pp. 137-138. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
The photolysis of (prophos)Cu-I(CO3)Cu-I(prophos) with prophos = 1,3-bis(diphenylphosphino)-propane in homogeneous solution leads to the reduction of carbonate according to a simple overall stoichiometry (CO2 + prophos -> CO + prophos monoxide). It is suggested that this reaction is initiated by a (Cu-1 -> CO32-) MLCT state. (C) 2009 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL-COMPLEXES; CO2; REDUCTION; DIOXIDE; Coordination chemistry; Copper(I); Photochemistry; Carbonate reduction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Aug 2020 08:56 |
| Last Modified: | 17 Aug 2020 08:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/25480 |
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