Biegerl, Andreas and Groger, Christian and Kalbitzer, Hans Robert and Wachter, Joachim and Zabel, Manfred (2010) Investigation of the Coordination Behavior of P4S3 towards CuBr. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 636 (5). pp. 770-774. ISSN 0044-2313,
Full text not available from this repository.Abstract
The formation of coordination polymers from copper(I) bromide and P4S3 a potentially tetradentate P donor bridging ligand was studied Whereas (P4S3)(3)(CuBr)(7) (1) formed in excellent yield, (P4S3)(CuBr)(3) (2) and (P4S3)(CuBr) (3) crystallized as mixtures The new compounds were characterized by X-ray crystallography and solid state P-31 MAS NMR spectroscopy The structure of 1 consists of a 3D network of cylindrical (CuBr)(n) columns castellated (CuBr)(n) chains and diatomic CuBr units These building blocks are linked by tetradentate P4S3 molecules The structure of 2 comprises undulated (CuBr) layers which are intra and interlayer linked by tridentate P4S3 molecules Compound 3 is a one dimensional polymer composed of four membered Cu2Br2 rings which are bridged by the P-3 bases of two P4S3 molecules
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; METAL-COMPLEXES; ETA(1)-P-BASAL COORDINATION; COPPER IODIDE; CAGE MOLECULE; SE MOLECULES; P4X3 X; LIGANDS; CHEMISTRY; FRAGMENTS; Phosphorus; Sulfur; Copper; Coordination polymers; Solid-state NMR spectroscopy |
| Subjects: | 500 Science > 540 Chemistry & allied sciences 500 Science > 570 Life sciences |
| Divisions: | Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie > Prof. Dr. Dr. Hans Robert Kalbitzer Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 27 Aug 2020 07:37 |
| Last Modified: | 27 Aug 2020 07:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/25634 |
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