Brunner, Henri and Weber, Matthias and Zabel, Manfred (2003) Enantioselective catalysis. Part 147. A Rh(cod) complex with the chiral [Pt2S2{(-)diop}(2)] ligand. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 684 (1-2). pp. 6-12. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The trinuclear complex [Pt2Rh(mu(3)-S)(2){(-)-diop}(2)(cod)]Cl (3) was synthesized starting from the chiral "ligand" [Pt-2(mu-S)(2){(-)-diop}] (2) and [Rh(cod)Cl](2), and characterized by X-ray crystallography. Compound 3 was used as a catalyst in the hydrosilylation of acetophenone with diphenylsilane and in the hydrogenation of ketopantolactone. (C) 2003 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL COMPLEXES; ASYMMETRIC CATALYSIS; STRUCTURAL CHARACTERIZATION; SULPHIDO-COMPLEXES; CRYSTAL-STRUCTURES; PT2S2 CORE; CHEMISTRY; DICHLOROMETHANE; TRANSFORMATION; PLATINUM(II); enantioselective catalysis; heterometallic complexes; platinum; rhodium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 27 Jul 2021 12:08 |
| Last Modified: | 27 Jul 2021 12:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38461 |
Actions (login required)
 |
View Item |
