Brunner, Henri and Zettler, Christian and Zabel, Manfred (2003) Asymmetric catalysis. Part 149. Synthesis of new chiral tridentate ligands for enantioselective catalysis. MONATSHEFTE FUR CHEMIE, 134 (9). pp. 1253-1269. ISSN 0026-9247
Full text not available from this repository. (Request a copy)Abstract
The synthesis of new chiral tridentate ligands is reported which coordinate transition metals in a meridional way. The ligands contain a pyridine ring, an oxazoline ring, and a strongly coordinating diphenylphosphanyl group. The methionine-derived ligand forms a copper complex, which has been studied by X-ray crystallography. The new ligands were tested in models of enantioselective catalyses, such as hydrogenation of ketopantolactone, hydrosilylation of acetophenone, and transfer hydrogenation of acetophenone.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSFER HYDROGENATION; PHOSPHINE-BORANES; EFFICIENT METHOD; COMPLEXES; HYDROSILYLATION; ACETOPHENONE; OXAZOLINE; KETONES; tridentate ligands; chirality; enantioselective catalysis; X-ray structure analysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jul 2021 11:10 |
| Last Modified: | 29 Jul 2021 11:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38678 |
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