HIGH-PRESSURE SYNTHESIS AND STRUCTURE REFINEMENT OF SRVO3, SR2VO4, AND SR3V2O7

RANGE, KJ and RAU, F and KLEMENT, U (1991) HIGH-PRESSURE SYNTHESIS AND STRUCTURE REFINEMENT OF SRVO3, SR2VO4, AND SR3V2O7. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 46 (10). pp. 1315-1318. ISSN 0932-0776,

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Abstract

Single crystals of SrVO3, Sr2VO4 and Sr3V2O7 have been obtained by high-pressure reactions in a modified belt-type apparatus. The crystal structures, refined from diffractometer data, are as follows: SrVO3, perovskite type, Pm 3BAR m, a = 3.8408(3) angstrom, R = 0.017, R(w) = 0.018, composition from occupancy refinement of oxygen positions SrVO2.93(2); Sr2VO4, K2NiF4 type, I 4/mmm, a = 3.837(1), c = 12.569(1) angstrom, R = 0.014, R(w) = 0.017; Sr3V2O7, Sr3Ti2O7 type, I 4/mmm, a = 3.839(1), c = 20.262(2) angstrom, R = 0.020, R(w) = 0.029.

Item Type: Article
Uncontrolled Keywords: ; STRONTIUM VANADIUM(IV) OXIDES; HIGH-PRESSURE SYNTHESIS; CRYSTAL STRUCTURE
Depositing User: Dr. Gernot Deinzer
Last Modified: 19 Oct 2022 08:46
URI: https://pred.uni-regensburg.de/id/eprint/54857

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