GUNTNER, W and GLIEMANN, G and KUNKELY, H and REBER, C and ZINK, JI (1990) ABSORPTION AND EMISSION-SPECTRA OF A SINGLE-CRYSTAL (MALEONITRILEDITHIOLATO)PALLADATE(II) COMPLEX. INORGANIC CHEMISTRY, 29 (26). pp. 5238-5241. ISSN 0020-1669,
Full text not available from this repository.Abstract
The polarized optical absorption and emission of single crystals of [(C2H5)4N]2[Pd(mnt)2] (mnt = [S2C2(CN)2]2-) at temperatures 3 K less-than-or-equal-to T less-than-or-equal-to 295 K are reported. The lowest excited states are due to 1,3B3g and 1,3B2u terms with metal-to-ligand charge-transfer and ligand-centered character, respectively. Vibronic structure is observed on the lowest energy absorption band and on the emission band. The energy spacings and the intensities of the vibronic bands are analyzed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | NICKEL; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/55194 |
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