BENEDIX, R and HENNIG, H and KUNKELY, H and VOGLER, A (1990) OPTICAL LIGAND-TO-LIGAND CHARGE-TRANSFER OF ZN(2,2'-BIPYRIDYL) (3,4-TOLUENEDITHIOLATE). CHEMICAL PHYSICS LETTERS, 175 (5). pp. 483-487. ISSN 0009-2614,
Full text not available from this repository.Abstract
The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn (2,2'-bipyridyl) (3,4-toluenedithiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalization between donor and acceptor ligand and charge separation by LLCT excitation depends on the mutual orientation of both ligands.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; COMPLEXES; SYSTEM; |
| Depositing User: | Dr. Gernot Deinzer |
| Last Modified: | 19 Oct 2022 08:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/55195 |
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