Gawron, Martin and Eder, Johannes and Weichselgartner, Xaver and Gschwind, Ruth M. and Wolf, Robert (2025) A Highly Reduced Magnesium Dicobalt Complex for the Hydrogenation of Tri- and Tetra-Substituted Alkenes. ORGANOMETALLICS, 44 (19). pp. 2141-2145. ISSN 0276-7333, 1520-6041
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The reaction of [K(thf)0.33][Co(eta 4-cod)2] (E; cod = 1,5-cyclooctadiene) with 0.5 equiv of MgCl2 led to the isolation of the magnesium dicobalt complex Mg[Co(eta 4-cod)2]2 (1). Complex 1 forms a tight ionic complex in the solid state and in toluene solution due to electrostatic interactions between the Mg2+ cation and the [Co(eta 4-cod)2]- anions. The complex is a successful precatalyst for the hydrogenation of sterically challenging tri- and tetra-substituted alkenes, surpassing the catalytic capabilities of related alkali metal and beta-diketiminate magnesium complexes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | HOMOGENEOUS CATALYSIS; AMINE-BORANE; COBALT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 19 May 2026 09:49 |
| Last Modified: | 19 May 2026 09:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/65894 |
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