Erhard, Alexander and Falge, Benjamin and Arp, Felice and Lucia-Tamudo, Jesus and Rittner, Thomas and Tapavicza, Enrico and Nuernberger, Patrick and Wolf, Robert (2025) Photochemical Arylation Reactions Mediated by a Terpyridine Cobalt Complex. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 28 (29): e202500398. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
The complex [CoII(4 '-MeO-tpy)2](PF6)2 (4 '-MeO-tpy = 4 '-methoxy-2,2 ':6 ',2 ''-terpyridine) effectively mediates the visible-light-driven arylation of pyrroles, 1,3,5-trimethoxybenzene, and bis(pinacolato)diborane (B2Pin2). Mechanistic studies suggest the reaction likely proceeds via a halogen atom transfer mechanism facilitated by an alpha-aminyl radical. This work highlights the potential of optimizing the ligand framework and reaction conditions to advance the application of earth-abundant transition metal complexes in photoredox catalysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOREDOX CATALYSIS; AMINOALKYL RADICALS; ACTIVATION; aryl halides; C-C bond formation; cobalt; photocatalysis; visible light |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Physical Chemistry I > Prof. Dr. Patrick Nürnberger |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 May 2026 05:46 |
| Last Modified: | 07 May 2026 05:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/65904 |
Actions (login required)
 |
View Item |
