Moussa, Mehdi Elsayed and Hegen, Oliver and Riesinger, Christoph and Scheer, Manfred (2025) Extended Synthetic Pathways Towards Dialkyl-Substituted Phosphanylboranes. INORGANICS, 13 (7): 239. ISSN 2304-6740
Full text not available from this repository. (Request a copy)Abstract
Phosphine-boranes have garnered growing interest for their potential in catalysis and as building blocks for inorganic polymers. While various synthetic methods exist, flexibility to introduce diverse substituents on the P centers remains limited. Our group reported routes to monoalkylated phosphanylboranes starting from primary phosphanylboranes or sodium phosphide. In this work, we extend these strategies to enable the synthesis of dialkylated phosphanylboranes bearing either identical or different substituents on the P atoms. This expanded methodology provides access to a broader scope of diverse P centers, a key factor influencing the reactivity and applications of phosphine-borane derivatives.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHINE-BORANE ADDUCTS; PHOSPHORUS; PHOSPHINOBORANES; REDUCTION; POLYMERS; REAGENTS; LIGANDS; CHAINS; ROUTE; alkylation; boron; phosphanylboranes; phosphonium salts; phosphorus |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Jun 2026 04:53 |
| Last Modified: | 17 Jun 2026 04:53 |
| URI: | https://pred.uni-regensburg.de/id/eprint/65968 |
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