Wieneke, Jan and Cirigliano, Francesco and Schorpp, Marcel (2025) A diazadiphospholenium cation featuring a reactive P[double bond, length half m-dash]P bond: synthesis and reversible main-group bond activation. CHEMICAL COMMUNICATIONS, 61 (90). pp. 17601-17604. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
We report a high-yielding synthesis of a novel diazadiphospholenium cation featuring a sterically exposed, reactive PP bond. It displays aromatic properties and greater reactivity and selectivity than its parent diphosphene, enabling selective [4+2] cycloaddition and unusual, reversible E-E bond scission in diphenyldichalcogenides, highlighting its potential for main-group bond activation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS; CRYSTAL; CHEMISTRY |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 May 2026 06:02 |
| Last Modified: | 05 May 2026 06:02 |
| URI: | https://pred.uni-regensburg.de/id/eprint/65976 |
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