Riesinger, Christoph and Scheer, Manfred (2025) Redox mediated dimerisation of a cyclo-As8 complex. CHEMICAL SCIENCE, 16 (20). pp. 8807-8811. ISSN 2041-6520, 2041-6539
Full text not available from this repository. (Request a copy)Abstract
Reduction as well as oxidation of the cyclo-As8 complex [{Cp '' Ta}2(mu,eta 2:2:2:2:1:1-As8)] (A, Cp '' = 1,3-tBu2C5H3) are demonstrated to afford controlled dimerisation to unprecedented As16 species. The dication [{Cp '' Ta}4(mu 4,eta 2:2:2:2:2:2:2:2:1:1:1:1-As16)]2+ slowly disproportionates in solution, yielding the largest polyarsenide species in a molecular complex known to date.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 May 2026 05:32 |
| Last Modified: | 06 May 2026 05:32 |
| URI: | https://pred.uni-regensburg.de/id/eprint/66152 |
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