Efficient detection of 1H, 15N correlations in hydrogen bonded low molecular catalyst-substrate intermediates without selective 15N-labelling

Scholtes, Christian L. and Ilgen, Julian and Gschwind, Ruth M. (2025) Efficient detection of 1H, 15N correlations in hydrogen bonded low molecular catalyst-substrate intermediates without selective 15N-labelling. CHEMICAL COMMUNICATIONS, 61 (38). pp. 6921-6924. ISSN 1359-7345, 1364-548X

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Abstract

To date, SOFAST approaches have generally been limited to biomolecules. We present the applicability of SOFAST-HMQC techniques to small molecules in the slow-tumbling regime offering a time-efficient characterization of catalyst substrate hydrogen bonds with nitrogen at natural abundance. This extends NMR access to a broader range of catalyst substrate combinations.

Item Type: Article
Uncontrolled Keywords: NMR; SPECTRA; PROTEINS; SYSTEMS; SCALE; ACIDS; TOOL
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 May 2026 06:39
Last Modified: 05 May 2026 06:39
URI: https://pred.uni-regensburg.de/id/eprint/66170

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