Mende, Michael and Cammarata, Jose and Scott, Daniel J. and Wolf, Robert (2025) One-pot synthesis of primary phosphines from white phosphorus. CHEMICAL COMMUNICATIONS, 61 (68). pp. 12721-12724. ISSN 1359-7345, 1364-548X
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Aryl and alkyl chlorides are inexpensive and readily accessible, making them ideal reagents for converting white phosphorus (P4) into primary phosphines RPH2. However, methods for achieving this transformation directly, bypassing undesired intermediates like PCl3, have remained elusive. This report describes the 'one-pot' synthesis of primary organophosphines from P4 using organotin compounds, including a multi-gram synthesis of PhPH2 featuring efficient recovery of organotin reagents for potential recycling.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SODIUM BIS(TRIMETHYLSILYL)AMIDE |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 May 2026 06:46 |
| Last Modified: | 05 May 2026 06:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/66560 |
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