Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Huber, Matthias and Kumar, Ajeet and Hauer, Juergen and Thyrhaug, Erling and Hess, Corinna R. (2025) Photoredox capacity expanded by the Cu site of CuFe-Mabiq. CHEMICAL COMMUNICATIONS, 61 (31). pp. 5731-5734. ISSN 1359-7345, 1364-548X

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Abstract

The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

Item Type: Article
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 May 2026 06:53
Last Modified: 05 May 2026 06:53
URI: https://pred.uni-regensburg.de/id/eprint/66727

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