Fedulin, Andrey and Luxenberger, Lea and von Wangelin, Axel Jacobi (2025) Chemospecific cobalt-catalyzed hydroboration of CO2. RSC ADVANCES, 15 (23). pp. 18512-18517. ISSN 2046-2069
Full text not available from this repository. (Request a copy)Abstract
A bifunctional cobalt pyridonate complex effectively catalyzes the hydroboration of CO2 to the boryl formate at very mild conditions (0.1-1 mol% cat., 1 bar CO2, r.t., 5 min, 100% yield, TON 1000, TOF 12 000 h-1). At higher temperature, clean conversion to the methoxyborane was achieved (98% yield). Mechanistic studies indicate formation of a ligand-derived cobalt hydride species.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Aug 2026 06:21 |
| Last Modified: | 11 Aug 2026 06:21 |
| URI: | https://pred.uni-regensburg.de/id/eprint/66853 |
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