Kurtanidze, Manoni and Butkhuzi, Tinatin and Rukhadze, Marina and Kokiashvili, Nino and Bezarashvili, George and Marcus, Julien and Kunz, Werner and Sigua, Ketevan (2017) Study of structural changes of water confined in Brij-30 reverse micelles: Revealing influence of ionic additives. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 519. pp. 98-105. ISSN 0927-7757, 1873-4359
Full text not available from this repository. (Request a copy)Abstract
The microenvironment of water droplets of nonionic polyoxyethylene (4) lauryl ether reverse micelles was investigated using infrared, ultraviolet-visible and nuclear magnetic resonance spectroscopy, also by dynamic light scattering. The different influence of kosmotropic and chaotropic ionic additives on the microstructure of reverse micelles was revealed. The values of chemical shift in the presence of structure-breaking perchlorate ions are higher than their values in case of structure-making acetate ions according to measurements by proton magnetic resonance spectroscopy. Deconvolution of the O-H stretching vibrational absorption spectra in the region of 3000-3800 cm(-1) into three sub peaks with a Monte Carlo method showed that perchiorate ions promote an increasing of free water fraction in the water pools of the reverse micelles, whereas acetate ions support formation of bound water. Influence of salt additives results in slight different sizes of water droplets, measured by dynamic light scattering method. Different influence of kosmotropic and chaotropic anions on binding constant K-b of optical probe to ethylene oxide groups was revealed. (C) 2016 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DYNAMIC LIGHT-SCATTERING; X-RAY-SCATTERING; SPECTROSCOPY; SYSTEMS; MICROEMULSIONS; ENVIRONMENTS; SURFACTANTS; CUMULANTS; H-1-NMR; BINDING; Brij-30 reverse micelle; Ionic additives; Chemical shift; Free and bound water; Sizes of water droplets; Binding constant |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:10 |
| Last Modified: | 15 Feb 2019 12:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1024 |
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