Rackl, Daniel and Kais, Viktor and Lutsker, Eugen and Reiser, Oliver (2017) Synthesis of Chiral Tetrahydrofurans and Pyrrolidines by Visible-Light-Mediated Deoxygenation. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (15). pp. 2130-2138. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
The synthesis of chiral tetrahydrofurans and pyrrolidines starting from 1,2-diols or -amino alcohols, respectively, by visible-light-mediated deoxygenation is described. Easily accessible monoallylated/propargylated substrates were activated either as inexpensive ethyl oxalates or as recyclable 3,5-bis(trifluoromethyl)benzoates to generate alkyl radicals suitable for 5-exo-trig/5-exo-dig cyclizations under visible-light irradiation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENANTIOSELECTIVE SYNTHESIS; PHOTOREDOX CATALYSIS; LEONTOPODIUM-ALPINUM; ALCOHOLS; ALKENOLS; OXALATES; COMPLEX; SYSTEM; ALKYL; Photocatalysis; Photochemistry; Radical reactions; Heterocycles; Electron transfer |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:10 |
| Last Modified: | 11 Feb 2019 13:58 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1027 |
Actions (login required)
 |
View Item |
