Meyer, Andreas Uwe and Lau, Vincent Wing-hei and Koenig, Burkhard and Lotsch, Bettina V. (2017) Photocatalytic Oxidation of Sulfinates to Vinyl Sulfones with Cyanamide-Functionalised Carbon Nitride. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (15). pp. 2179-2185. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
The cyanamide-functionalised carbon nitride (NCN-CNx) can be employed as a photo-redox catalyst for the light-induced sulfonylation of alkenes with sulfinate salts, attaining product yields twice those obtained with the non-functionalised counterpart and comparable to those achieved with the benchmark homogeneous photocatalyst Eosin Y. NCN-CNx as a heterogeneous photocatalyst is easily isolatable and can be re-used for this reaction for over three cycles. This photocatalytic reaction can proceed with various sulfinates (aryl-, alkyl- and thiophene-based) and alkenes with electron-donating and -withdrawing groups, obtaining good to excellent product yields. A reductive quenching route was determined to be the likely mechanism for this photocatalyst.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; ORGANIC-SYNTHESIS; HYDROGEN-PRODUCTION; CHEMICAL-SHIFTS; H-2 PRODUCTION; NI CATALYST; EOSIN Y; COMPLEXES; GENERATION; Heterogeneous catalysis; Photocatalysis; Alkenes; Sulfonylation; Reaction mechanisms; Oxidation |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:10 |
| Last Modified: | 11 Feb 2019 14:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1029 |
Actions (login required)
 |
View Item |
