Malberg, Jennifer and Bodensteiner, Michael and Paul, Daniel and Wiegand, Thomas and Eckert, Hellmut and Wolf, Robert (2014) Preparation of an Organometallic Molecular Square by Self-Assembly of Phosphorus-Containing Building Blocks. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53 (10). pp. 2771-2775. ISSN 1433-7851, 1521-3773
Full text not available from this repository. (Request a copy)Abstract
Molecular squares are among the most common supramolecular architectures, but phospha-organometallic complexes have not been used as building blocks for this type of structure. Herein we describe the formation of the molecular square [Au{Co(P(2)C(2)tBu(2))(2)}](4) (1) by the self-assembly of anionic 1,3-diphosphacyclobutadiene cobalt complexes and gold(I) cations. The X-ray crystallographic determination of the molecular structure of 1 is complemented by solid-state P-31 and (CNMR)-C-13 investigations. High-level DFT calculations confirm the assignment of the P-31 and (CNMR)-C-13 resonances.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ORDER REGULAR APPROXIMATION; CRYSTAL-STRUCTURES; NMR-SPECTRA; COMPLEXES; LIGANDS; GEOMETRY; CHEMISTRY; CATALYSIS; GOLD(I); cobalt; gold; metallomacrocycles; sandwich complexes; self-assembly |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 18 Nov 2019 09:35 |
| Last Modified: | 18 Nov 2019 09:35 |
| URI: | https://pred.uni-regensburg.de/id/eprint/10483 |
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