Polyoxygenated seco-cyclohexenes and other constituents from Uvaria valderramensis

Macabeo, Allan Patrick G. and Rubio, Peter Yuosef M. and Higuchi, Tsunehiko and Umezawa, Naoki and Faderl, Christian and Budde, Simon and Bangcaya, Porferio S. and Alejandro, Grecebio Jonathan D. (2017) Polyoxygenated seco-cyclohexenes and other constituents from Uvaria valderramensis. BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 71. pp. 200-204. ISSN 0305-1978, 1873-2925

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Abstract

Phytochemical study on the Philippine endemic Annonaceae plant Uvaria valderramensis afforded a new highly oxygenated seco-cydohexene derivative, valderepoxide (1), along with the six known compounds uvamalols D (2) and G (3), grandiuvarone (4), 2'-hydroxy3',4',6'-trimethoxychalcone (5), valderramenol B (6) and benzoic acid. The structure of 1 was determined through extensive spectroscopic analyses including 1D, 2D NMR and HRESIMS. Its relative stereochemistry was established using 2D-NOESY. This is the first report on the isolation of polyoxygenated compounds 1-3 and chalcone 5 from U. valderramensis. (C) 2017 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ANNONACEAE; DERIVATIVES; RUFA; Uvaria valderramensis; Annonaceae; Chemotaxonomy; Valderepoxide; Seco-cyclohexenes; Chalcones
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Dec 2018 13:11
Last Modified: 19 Feb 2019 10:48
URI: https://pred.uni-regensburg.de/id/eprint/1080

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