Novel ruthenium-catalyst for hydroesterification of olefins with formates

Profir, Irina and Beller, Matthias and Fleischer, Ivana (2014) Novel ruthenium-catalyst for hydroesterification of olefins with formates. ORGANIC & BIOMOLECULAR CHEMISTRY, 12 (36). pp. 6972-6976. ISSN 1477-0520, 1477-0539

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Abstract

An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthenium complex has been isolated and characterized.

Item Type: Article
Uncontrolled Keywords: CHELATION-ASSISTED HYDROESTERIFICATION; CARBON-MONOXIDE; METHYL FORMATE; ALKENES; EFFICIENT; CARBONYLATION; HYDROCARBAMOYLATION; COMPLEXES; ETHYLENE; LIGANDS;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Nov 2019 08:59
Last Modified: 29 Nov 2019 08:59
URI: https://pred.uni-regensburg.de/id/eprint/10950

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