Heinl, Sebastian and Scheer, Manfred (2014) Activation of group 15 based cage compounds by [(CpFe)-Fe-BIG(CO)(2)] radicals. CHEMICAL SCIENCE, 5 (8). pp. 3221-3225. ISSN 2041-6520, 2041-6539
Full text not available from this repository. (Request a copy)Abstract
The sterically encumbered dimer [(CpFe)-Fe-BIG(CO)(2)(]2) (1) (Cp-BIG C-5(4-nBuC(6)H(4))(5)) is able to activate small tetrahedral molecules like P-4 and As-4 as well as the less reactive cage compounds P4S3 and P4Se3 at room temperature to give the products [{CpBIGFe(CO) 2} 2(m, h 1: 1- (c)age)] (cage P-4 (2a), As-4 (2b), P4S3 (2c), P4Se3 (2d)) in a quantitative manner. The reaction proceeds via selective cleavage of one E- E bond (E P, As) of the starting material. Complex 1 also reacts with CS2 forming the binuclear compound [{CpBIGFe(CO 2}{CpBIGFeCO}(m, h 1: 2-CS2)] (3).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS BOND-CLEAVAGE; MAIN-GROUP ELEMENTS; WHITE PHOSPHORUS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; CARBON-DISULFIDE; P-4 ACTIVATION; METAL-COMPLEXES; LIGANDS; P4S3; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Nov 2019 08:54 |
| Last Modified: | 29 Nov 2019 08:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/10970 |
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