Pelties, Stefan and Herrmann, Dirk and de Bruin, Bas and Hartl, Frantisek and Wolf, Robert (2014) Selective P-4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides. CHEMICAL COMMUNICATIONS, 50 (53). pp. 7014-7016. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P-4 results in a nickel tetraphosphide [{CpNi(IDipp)}(2)(mu-eta(1):eta(1)-P-4)] with a butterfly-P-4(2)-ligand; related chalcogenides [{CpNi(IDipp)}(2)(mu-E-2)] (E = S, Se, Te) and [{CpNi(IDipp)}(2)(mu-E-3)] (E = S, Se) are formed with S-8, Se-infinity and Te-infinity.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | N-HETEROCYCLIC CARBENES; WHITE PHOSPHORUS; ELECTRONIC-STRUCTURE; RUTHENIUM COMPLEXES; D(9) COMPLEXES; METAL-COMPLEX; REACTIVITY; LIGAND; IRON; TRANSFORMATION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Nov 2019 10:19 |
| Last Modified: | 29 Nov 2019 10:19 |
| URI: | https://pred.uni-regensburg.de/id/eprint/10989 |
Actions (login required)
 |
View Item |
