Rad, Babak Rezaei and Herrmann, Dirk and Lescop, Christophe and Wolf, Robert (2014) A tetradentate metalloligand: synthesis and coordination behaviour of a 2-pyridyl-substituted cyclobutadiene iron complex. DALTON TRANSACTIONS, 43 (11). pp. 4247-4250. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The salt [K([18]crown-6){Cp*Fe(eta(4)-C(4)py(4))}] (K1, py = 2-pyridyl, Cp* = C5Me5) is accessible by the reaction of an iron(0) naphthalene precursor and bis(2-pyridyl)acetylene. Cyclic voltammetry and preparative investigations demonstrate the electron-rich nature of K1, which is reversibly oxidized to neutral [Cp*Fe(eta(4)-C(4)py(4))] (1) at a low potential. The first coordination studies with iron(II) and zinc(II) chloride show that all four 2-pyridyl units may be employed for metal coordination.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METALS; CP-ASTERISK; NAPHTHALENE; PHOSPHORUS; REACTIVITY; CHEMISTRY; LIGANDS; ANION; LEAD; FE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Nov 2019 11:25 |
| Last Modified: | 29 Nov 2019 11:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/11039 |
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