Martinez-Triana, Yeimy M. and Whelan, Rory and Finn, M. G. and Diaz, David Diaz (2017) Glass-Metal Adhesive Polymers from Copper(I)-Catalyzed Azide-Alkyne Cycloaddition. MACROMOLECULAR CHEMISTRY AND PHYSICS, 218 (8): UNSP 16005. ISSN 1022-1352, 1521-3935
Full text not available from this repository. (Request a copy)Abstract
Cu(I)-catalyzed azide-alkyne cycloaddition is shown here to be an efficient method to create adhesive materials in situ between glass and copper surfaces. Twelve formulations show adhesive strengths greater than a commercial product under comparable conditions, with the best combination of monomers the same as that previously developed for copper-copper adhesion. Strong adhesion is also achieved under water, an environment in which the commercial glue fails. Brass, iron, and stainless steel could also be adhered to glass using different formulations, but aluminum could not. The concentration and molar ratio of monomers, curing temperature, prefunctionalization of the glass surface, and the incorporation of flexibility-inducing components all have significant effects on adhesive performance.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRIAZOLE DERIVATIVE INHIBITORS; CLICK CHEMISTRY; 1,3-DIPOLAR CYCLOADDITIONS; PITTING CORROSION; TERMINAL ALKYNES; COPPER; POLYMERIZATION; STRENGTH; LIGANDS; SURFACE; adhesion; click chemistry; copper; glass; metal; polymers; polytriazoles |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. David Díaz Díaz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:11 |
| Last Modified: | 11 Feb 2019 14:19 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1105 |
Actions (login required)
 |
View Item |
