Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids

Gieshoff, Tim N. and Welther, Alice and Kessler, Michael T. and Prechtl, Martin H. G. and Jacobi von Wangelin, Axel (2014) Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids. CHEMICAL COMMUNICATIONS, 50 (18). pp. 2261-2264. ISSN 1359-7345, 1364-548X

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Abstract

Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.

Item Type: Article
Uncontrolled Keywords: CROSS-COUPLING REACTIONS; METAL NANOPARTICLES; ORGANIC-SYNTHESIS; STABILIZATION; PARTICLES; COMPLEXES;
Subjects: 600 Technology > 610 Medical sciences Medicine
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 02 Dec 2019 09:37
Last Modified: 02 Dec 2019 09:37
URI: https://pred.uni-regensburg.de/id/eprint/11056

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