Seitz, Andreas E. and Vogel, Ulf and Eberl, Miriam and Eckhardt, Maria and Balazs, Gabor and Peresypkina, Eugenia V. and Bodensteiner, Michael and Zabel, Manfred and Scheer, Manfred (2017) Coordination Behavior of [Cp '' Zr-2(eta(1:1)-P-4)] towards Different Lewis Acids. CHEMISTRY-A EUROPEAN JOURNAL, 23 (43). pp. 10319-10327. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
A detailed method for the preparation of [Cp '' Zr-2(eta(1:1)-P-4)](1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordi- nation modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; TETRAHEDRO-TETRAPHOSPHORUS; WHITE PHOSPHORUS; CYCLO-TRIPHOSPHORUS; MOLECULAR-STRUCTURE; LIGAND COMPLEXES; P-4 ACTIVATION; DINITROGEN; CHEMISTRY; ELEMENTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:16 |
| Last Modified: | 11 Feb 2019 14:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1463 |
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