Plokhikh, I. V. and Charkin, D. O. and Verchenko, V. Yu. and Kuznetsov, A. N. and Tsirlin, A. A. and Kazakov, S. M. and Shevelkov, A. V. (2018) Synthesis, crystal structure and physical properties of europium - manganese fluoride pnictides, EuMnPnF (Pn = P, As, Sb). JOURNAL OF SOLID STATE CHEMISTRY, 258. pp. 682-690. ISSN 0022-4596, 1095-726X
Full text not available from this repository. (Request a copy)Abstract
The quaternary compounds EuMnPnF (Pn = P, As, Sb) have been prepared via solid state route at 1173 K, and their crystal and electronic structures as well as magnetic and transport properties have been elucidated. These compounds belong to the widespread LaAgSO structure type and crystallize in tetragonal (P4/nmm) unit cells with a = 4.0292(1) angstrom, c = 8.9505(2) angstrom for EuMnPF, a = 4.1227(1) angstrom, c = 9.0846(2) angstrom for EuMnAsF, and a = 4.3120(1) angstrom, c = 9.4356(2) angstrom for EuMnSbF. At low temperatures, the magnetic response is dominated by Eu2+. Contrary to previous reports, we do not observe any magnetic transitions in EuMnPF down to 2 K, whereas its arsenide and antimonide analogs exhibit Eu2+ ordering around 3 K. According to the electrical resistivity measurements and density-functional calculations, all three compounds are narrow-gap semiconductors.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ZRCUSIAS; OXYPNICTIDES; CE; ND; Solid state synthesis; Layered structures; Electronic structure; Calculations; Magnetic measurements; Eu compounds |
| Subjects: | 600 Technology > 615 Pharmacy |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 20 Mar 2020 12:24 |
| Last Modified: | 20 Mar 2020 12:24 |
| URI: | https://pred.uni-regensburg.de/id/eprint/15127 |
Actions (login required)
 |
View Item |
