Moussa, Mehdi Elsayed and Fleischmann, Martin and Peresypkina, Eugenia V. and Duetsch, Luis and Seidl, Michael and Balazs, Gabor and Scheer, Manfred (2017) Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)(4)(eta(2)-P-2)] Complex and Silver(I) Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (25). pp. 3222-3226. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}(3)] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][TEF](2) (2) dimer and the [Ag-2(eta(1):eta(1)-1)(3)](n)[TEF](2n) (3) coordination polymer, whereas the second reaction afforded the [Ag-2(eta(1):eta(1)-1)(2)(eta(1)-CH2Cl2)(2)(eta(2)-C7H8)(2)][FAl](2) (4) or the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][FAl](2) (5) dimer and the [Ag-2(eta(1):eta(1)-1)(4)](n)[FAl](2n) (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/ or the synthetic procedure.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ORGANIC HYBRID MATERIALS; ONE-DIMENSIONAL POLYMERS; LIGAND COMPLEXES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; PENTAPHOSPHAFERROCENE; FRAMEWORKS; CHEMISTRY; MOLECULE; BEHAVIOR; Phosphorus; Coordination polymers; Coordinating anions; Silver; Synthetic methods |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:16 |
| Last Modified: | 11 Feb 2019 14:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1552 |
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