Kunkely, Horst and Vogler, Arnd (2013) Photoreduction of CO to Methanol. The Photolysis of Aqueous Solutions of [Os(NH3)(5)(CO)](2+). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 68 (12). pp. 1371-1374. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
The carbonyl complex [O-S(II)(NH3)(5)(CO)](2+) undergoes a photolysis in aqueous solution which yields [O-S(VI)(NH3)(4)N](3+) (Phi = 10(-3) at lambda(irr) = 255 nm) and methanol. This photoreduction of CO to CH3OH represents a novel type of photoreactivity of metal carbonyl complexes and could be utilized for an artificial photosynthesis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | RAY CRYSTAL-STRUCTURE; COORDINATED DINITROGEN; COMPLEXES; OSMIUM(II); PHOTOCHEMISTRY; HYDROGENATION; MODEL; Photochemistry; Osmium Complexes; Metal Carbonyl Complexes; CO Reduction; Artificial Photosynthesis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Mar 2020 10:00 |
| Last Modified: | 23 Mar 2020 10:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/15548 |
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