Herrmann, Josef M. and Koenig, Burkhard (2013) Reductive Deoxygenation of Alcohols: Catalytic Methods Beyond Barton-McCombie Deoxygenation. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013 (31). pp. 7017-7027. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
Deoxygenation is an extensively studied field in organic chemistry, and over the last decades many methods such as the Barton-McCombie deoxygenation reaction or deoxygenation with alkali metals in liquid ammonia have been established. Within this microreview, we discuss different strategies for the chemoselective catalytic deoxygenation of alcohols with special attention to their scope and limitations. The deoxygenation of derivatives of alcohols and their direct deoxygenation as step-economic alternative are covered with current examples. Catalytic methods can serve as convenient and economic alternatives for established methods in the reduction of carbon-oxygen single bonds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHENOLIC HYDROXYL-GROUPS; CARBON DOUBLE-BONDS; HYDRIODIC ACID; BENZYLIC ALCOHOLS; CHEMOSELECTIVE HYDROGENATION; SELECTIVE DEOXYGENATION; HETEROGENEOUS CATALYSIS; ARYL KETONES; FORMIC-ACID; OXYGEN BOND; Synthetic methods; Heterogeneous catalysis; Homogeneous catalysis; Alcohols; Chemoselectivity |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Petra Gürster |
| Date Deposited: | 19 Jun 2020 08:23 |
| Last Modified: | 19 Jun 2020 08:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/15726 |
Actions (login required)
 |
View Item |
