Guelak, Samet and Gieshoff, Tim N. and Jacobi von Wangelin, Axel (2013) Olefin-Assisted Iron-Catalyzed Alkylation of Aryl Chlorides. ADVANCED SYNTHESIS & CATALYSIS, 355 (11-12). pp. 2197-2202. ISSN 1615-4150, 1615-4169
Full text not available from this repository. (Request a copy)Abstract
A selective and operationally simple iron-catalyzed cross-coupling of aryl chlorides with alkylmagnesium halides has been developed. The reaction tolerates various functional groups and exhibits high chemoselectivity even in the presence of aryl bromides. Mechanistic studies indicate the essential role of the olefin substituent for substrate activation. Competing polymerization and reduction are effectively suppressed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CROSS-COUPLING REACTIONS; GRIGNARD-REAGENTS; ANIONIC-POLYMERIZATION; REDUCTIVE ELIMINATION; EFFICIENT SYNTHESIS; BOND FORMATION; STYRENE; ALKENES; HALIDES; CARBOMETALATION; cross-coupling; Grignard reactions; iron; olefin complexes; styrenes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Apr 2020 10:52 |
| Last Modified: | 02 Apr 2020 10:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/16231 |
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