Kachkovskyi, Georgiy and Faderl, Christian and Reiser, Oliver (2013) Visible Light-Mediated Synthesis of (Spiro)anellated Furans. ADVANCED SYNTHESIS & CATALYSIS, 355 (11-12). pp. 2240-2248. ISSN 1615-4150, 1615-4169
Full text not available from this repository. (Request a copy)Abstract
Visible light-mediated decarboxylation using N-acyloxyphthalimides as the source for carbon-centered radicals was applied for the synthesis of spirobutenolides. The utility of this approach is demonstrated with the formal synthesis of (S)-(+)-lycoperdic acid. Alternatively, 2,3-anellated furans can be obtained in a one-pot procedure via photocyclization following a regioselective semipinacol rearrangement.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | C-H ARYLATION; ELECTRON-TRANSFER; PHOTOREDOX CATALYSIS; STEREOSELECTIVE-SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; SINGLE-LAYER; ACID; PHOTOCATALYSIS; DECARBOXYLATION; PHOTOCHEMISTRY; butenolides; green chemistry; photoredox catalysis; semipinacol rearrangement; sensitization; spirocyclization |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Apr 2020 10:54 |
| Last Modified: | 02 Apr 2020 10:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/16232 |
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