Kunkely, Horst and Vogler, Arnd (2013) Photooxidation of Methane to Methanol by Perrhenate in Water under Ambient Conditions. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 68 (8). pp. 891-894. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
The oxidation of methane to methanol takes place selectively by the photolysis of perrhenate in aqueous solution in the presence of methane. This photoreaction is formally an oxygen atom transfer. Because the reoxidation of the reduced perrhenate is accomplished with hydrogen peroxide the overall process can be viewed as photocatalytic oxidation of methane to methanol: CH4 H2O2 -> CH3OH + H2O.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHARGE-TRANSFER EXCITATION; TRANSITION-METALS; OSMIUM-TETROXIDE; ACTIVATION; FUNCTIONALIZATION; PHOTOREACTIVITY; PHOTOCHEMISTRY; OXIDATION; COMPLEXES; BONDS; Rhenium Complexes; Photochemistry; Methane; Catalysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Apr 2020 12:36 |
| Last Modified: | 02 Apr 2020 12:36 |
| URI: | https://pred.uni-regensburg.de/id/eprint/16257 |
Actions (login required)
 |
View Item |
