Vannada, Jagadeshwar and Niehues, Lennart and Koenig, Burkhard and Mehta, Goverdhan (2013) A total synthesis of the epoxyquinone natural product cytosporin D. TETRAHEDRON, 69 (30). pp. 6034-6040. ISSN 0040-4020,
Full text not available from this repository. (Request a copy)Abstract
A synthesis of epoxyquinone natural product cytosporin D from the readily available Diels-Alder adduct of cyclopentadiene and 2-prenyl-p-benzoquinone, has been accomplished. This approach leverages the stereochemical predisposition of the norbornyl-fused systems towards convex face reactivity as an enabler for the stereoselective construction of the pyran ring. (C) 2013 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENANTIOSELECTIVE TOTAL-SYNTHESIS; NF-KAPPA-B; CONVERTING-ENZYME INHIBITORS; UBIQUITIN-ACTIVATING ENZYME; FARROWIA SP. E-1941; BIOLOGICAL-PROPERTIES; FUNGAL METABOLITES; BUILDING-BLOCKS; FLUOSTATIN-C; DIMER; Epoxyquinone natural products; Diels-Alder reaction; Stereoselective reduction; Wittig olefination; Oxycylization |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Apr 2020 07:19 |
| Last Modified: | 06 Apr 2020 07:19 |
| URI: | https://pred.uni-regensburg.de/id/eprint/16348 |
Actions (login required)
 |
View Item |
