Graf, Marion and Gothe, Yvonne and Metzler-Nolte, Nils and Czerwieniec, Rafal and Suenkel, Karlheinz (2017) Bis-cyclometalated rhodium- and iridium-complexes with the 4,4 '-dichloro-2,2 '-bipyridine ligand. Evaluation of their photophysical properties and biological activity. INORGANICA CHIMICA ACTA, 463. pp. 36-43. ISSN 0020-1693, 1873-3255
Full text not available from this repository. (Request a copy)Abstract
The synthesis and characterization of new cyclometalated complex salts [M(C boolean AND N)(2)(4,4',-Cl(2)bpy)]PF6 (M = Rh and Ir; CAN = 2-(p-tolyl)pyridinato (1 and 2), 2-phenyl-5-chloro-pyridinato (3 and 4); 4,4'-Cl(2)bpy = 4,4'-dichloro-2,2'-bipyridine) is described. Compounds 1-4 were obtained by reaction of 4,4'dichloro-2,2'-bipyridine with the complexes [{M(mu-Cl)(C boolean AND N)(2)}(2)] (M = Rh, Ir) in refluxing CH2Cl2/MeOH mixtures. The molecular structures of compounds 1 and 4 were confirmed by X-ray diffraction. The Ir compounds show phosphorescence in PMMA film and in solution at ambient temperature. Furthermore, all compounds display significant cytotoxicity against human cancer cell lines with the IC50 values in the 0.4-2 mu M range. (C) 2017 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | EFFECTIVE CORE POTENTIALS; ELECTROCHEMICAL PROPERTIES; MOLECULAR CALCULATIONS; BASIS-SETS; DENSITY; 1,10-PHENANTHROLINE; SPECTROSCOPY; ABSORPTION; RESOLUTION; DISCOVERY; Cyclometalated complexes; Rhodium; Iridium; Phosphorescence; Cytotoxicity |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:16 |
| Last Modified: | 19 Feb 2019 13:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1655 |
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