Guentner, Christian and Korber, Nikolaus (2013) The first alkali metal hydroxide-ammoniate, cesium hydroxide-ammoniate (1:1), CsOH center dot NH3, synthesis and crystal structure. MONATSHEFTE FUR CHEMIE, 144 (6). pp. 747-750. ISSN 0026-9247,
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Cesium hydroxide-ammoniate (1:1), CsOH center dot NH3, was obtained as a side product in the reaction of cesium hydride, CsH and telluric acid, Te(OH)(6) in liquid ammonia at -38 A degrees C. The compound crystallizes as colorless crystals in the monoclinic space group P2(1)/c with Z = 8, a = 4.391(9) , b = 18.593(4) , c = 8.141 (16) , beta = 90.37(3)A degrees, and V = 664.6(24) (3). The crystal structure was solved from single crystal X-ray data. The structure contains a three-dimensional network built up by contacts between cesium cations and hydroxide anions and ammonia molecules, which in turn are connected by O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; Alkali metal; Hydrogen bonds; Crystal structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Apr 2020 04:58 |
| Last Modified: | 09 Apr 2020 04:58 |
| URI: | https://pred.uni-regensburg.de/id/eprint/16622 |
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