Moussa, Mehdi Elsayed and Attenberger, Bianca and Seidl, Michael and Schreiner, Anderea and Scheer, Manfred (2017) Discrete and Polymeric Organometallic-Organic Hybrid Materials Based on the Diphosphorus Complex [Cp2Mo2(CO)(4)((2)-P-2)], Cu-I Salts, and 2,2-Bipyrimidine. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (47). pp. 5616-5620. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
The reaction of the diphosphorus complex [Cp2Mo2(CO)(4)((2)-P-2)] (1), with the Cu-I salts [Cu(CH3CN)(4)][BF4] or [Cu(CH3CN)(4)][PF6], and a mixture of [Cu(CH3CN)(4)][BF4] and CuCl in the presence of 2,2-bipyrimidine (2) is studied. Depending on the Cu-I salts used and the layering solvent involved in the crystallisation, a variety of novel coordination compounds are accessible in moderate to excellent yields (26-80%): the novel dicationic molecular organometallic-organic hybrid complexes [{Cp2Mo2(CO)(4)(mu(3),(1:2:2)-P-2)}(4)(mu(2),(1:1:1:1)-C8H6N4)Cu-2][BF4](2) (3) and [{Cp2Mo2(CO)(4)(mu(3),(1:2:2)-P-2)}(2){Cp2Mo2(CO)(4)(mu(3),(2:2:2)-P-2)}(2)(mu(2),(1:1:1:1)-C8H6N4)Cu-2][PF6](2) (4), the unique neutral 1D organometallic-organic hybrid polymer [{Cp2Mo2(CO)(4)(mu(4),(1:1:2:2)-P-2)}(2)(mu(2),(1:1:1:1)-C8N6N4)(CuCl)(2)](n) (5) and the unprecedented 2D organometallic-organic hybrid polymer [{Cp2Mo2(CO)(4)(mu(4),(1:1:2:2)-P-2)}(mu(2),(1:1:1:1)-C8H6N4){Cu-2(mu-Cl)}](2)[BF4](2n) (6).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ONE-DIMENSIONAL POLYMERS; FULLERENE TOPOLOGY; BUILDING-BLOCKS; COORDINATION; LIGAND; DICHLOROMETHANE; FRAMEWORKS; PENTAPHOSPHAFERROCENE; SUPRAMOLECULE; CONSTRUCTION; Diphosphorus complex; Neutral hybrid polymer; Copper(I); Coordination polymers |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:18 |
| Last Modified: | 11 Feb 2019 14:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1672 |
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