Fendt, Franziska and Koch, Carina and Gaertner, Stefanie and Korber, Nikolaus (2013) Reaction of Sn-4(4-) in liquid ammonia: the formation of Rb-6[(eta(2)-Sn-4)Zn(eta(3)-Sn-4)]center dot 5NH(3). DALTON TRANSACTIONS, 42 (44). pp. 15548-15550. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The reaction of Rb4Sn4 with ZnPh2 in liquid ammonia in the presence of [2.2.2]-cryptand yielded crystals of Rb-6[(eta(2)-Sn-4)Zn(eta(3)-Sn-4)]center dot 5NH(3), which could be characterized by single crystal X-ray diffraction. This is the first example of a successful solution reaction of the highly charged tetrahedral Sn-4(4-) anions. The homoleptic [E4ZnE4](6-) complex (E = tetrel element) was previously known only for E=Ge and Si/Ge.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | GROUP 15 ELEMENTS; CRYSTAL-STRUCTURE; ZINTL PHASE; TETRAHEDRO-TETRASTANNIDE; SOLUTION CHEMISTRY; CLUSTERS; RB; REFINEMENT; IONS; CS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Apr 2020 11:37 |
| Last Modified: | 28 Apr 2020 11:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/17347 |
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