Gaertner, Dominik and Konnerth, Hannelore and Jacobi von Wangelin, Axel (2013) Highly practical iron-catalyzed C-O cleavage reactions. CATALYSIS SCIENCE & TECHNOLOGY, 3 (10). pp. 2541-2545. ISSN 2044-4753,
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Facile iron-catalyzed cleavage of various allyl, cinnamyl and benzyl C-O linkages has been effected in the presence of ethylmagnesium chloride. The protocol is operationally simple (xylene-THF, r.t., 1 h), requires low catalyst loading (1 mol% FeCl2) and tolerates halides, esters, amines, ethers and olefins. The allyl moiety is converted to volatile hydrocarbons which renders laborious product separation unnecessary.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CROSS-COUPLING REACTIONS; ARYL GRIGNARD-REAGENTS; ALLYL ETHERS; ALKYL-HALIDES; SELECTIVE CLEAVAGE; PROTECTING GROUPS; FACILE; COMPLEXES; OLEFINS; ISOMERIZATION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Apr 2020 05:03 |
| Last Modified: | 29 Apr 2020 05:03 |
| URI: | https://pred.uni-regensburg.de/id/eprint/17365 |
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