Rozhkova, Yulia and Gurinov, Andrey A. and Tolstoy, Peter M. and Denisov, Gleb S. and Shenderovich, Ilya G. and Korotkov, Valentin I. (2013) Acridine - a Promising Fluorescence Probe of Non-Covalent Molecular Interactions. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 227 (6-7). pp. 857-868. ISSN 0942-9352,
Full text not available from this repository. (Request a copy)Abstract
Fluorescence and absorption spectral parameters of acridine have been studied in solution at room temperature in the presence of different proton donors aiming to inspect whether or not acridine can be used as a spectroscopic probe suitable to measure the geometry of hydrogen bonds under different conditions. It has been shown that the most appropriate spectral parameter is the position of fluorescence maximum that changes heavily upon a contraction of the N. . .H distance. Presumably, also the intensity of the maximum strongly depends on the hydrogen bond geometry. These two parameters can be used to establish two independent, mutually complementary correlations connecting the spectral manifestations and the geometry of hydrogen bond.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | INTRAMOLECULAR PROTON-TRANSFER; HYDROGEN-BOND GEOMETRIES; NMR CHEMICAL-SHIFTS; CARBOXYLIC-ACIDS; STRETCHING FREQUENCIES; MESOPOROUS SILICA; INFRARED-SPECTRA; STATE; COMPLEXES; WATER; Hydrogen Bond; Acridine; Acid-Base Complexes; Fluorescence; Proton Transfer |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Apr 2020 05:19 |
| Last Modified: | 29 Apr 2020 05:19 |
| URI: | https://pred.uni-regensburg.de/id/eprint/17386 |
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