Smith, Charlene A. and Tuna, Floriana and Bodensteiner, Michael and Helliwell, Madeleine and Collison, David and Layfield, Richard A. (2013) Exchange-coupled oxygen- and sulfur-bridged cyclopentadienyl-manganese(II) cages. DALTON TRANSACTIONS, 42 (1). pp. 71-74. ISSN 1477-9226,
Full text not available from this repository. (Request a copy)Abstract
The trimetallic complex [{CpMn(mu-OSiPh3)(2)}(2)Mn] (1) and the heterocubane [CpMn(mu(3)-SSiPh3)](4) (2) are formed by deprotonation of Ph(3)SiQH (Q = O, S) by manganocene, or by transmetallation of manganocene by Ph(3)SiQLi. The Mn(II) centres in 1 and 2 are antiferromagnetically coupled, with J = -4.4 and -3.0 cm(-1) in 1 and 2, respectively (-2J formalism).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SINGLE-MOLECULE MAGNETS; CHALCOGENIDE CLUSTERS; COMPLEXES; MANGANESE(II); MN(II); C5H5; CP; MONONUCLEAR; MANGANOCENE; CHEMISTRY; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Apr 2020 05:16 |
| Last Modified: | 30 Apr 2020 05:16 |
| URI: | https://pred.uni-regensburg.de/id/eprint/17542 |
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