Graf, Marion and Boettcher, Hans-Christian and Mayer, Peter and Scheer, Manfred (2017) Synthesis and Molecular Structures of [Rh(eta(5)-C5H5)(coe)(2)] (coe = cis-cyclooctene) and [Rh(eta(5)-C5H5)(cod)] (cod = cis,cis-eta(4)-1,5-cyclooctadiene). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 643 (21). pp. 1323-1325. ISSN 0044-2313, 1521-3749
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The synthesis and structural characterization of the new olefinic complex [Rh(eta(5)-C5H5)(coe)(2)] (2) (coe = cis-cyclooctene) is reported. The title compound could easily be prepared in good yield by reaction of [{Rh(mu-Cl)(coe)(2)}(2)] (1) with an appropriate amount of thallium cyclopentadienide in THF at room temperature. Single crystals of 2 were grown from n-hexane and were analyzed by X-ray crystallography. In a similar manner the compound [Rh(eta(5)-C5H5)(cod)] (4) (cod = cis, cis-1.5-cyclooctadiene) was obtained from [{Rh(mu-Cl)(cod)}(2)] and thallium cyclopentadienide in THF at room temperature and was characterized by spectroscopic means as well as by X-ray diffraction.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; RHODIUM; EXCHANGE; Cyclopentadienyl complex; Olefin complex; Crystal structure; Rhodium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:19 |
| Last Modified: | 11 Feb 2019 14:58 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1836 |
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