Moussa, Mehdi Elsayed and Seidl, Michael and Balazs, Gabor and Zabel, Manfred and Virovets, Alexander V. and Attenberger, Bianca and Schreiner, Andrea and Scheer, Manfred (2017) Preorganized Ag-I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers. CHEMISTRY-A EUROPEAN JOURNAL, 23 (64). pp. 16199-16203. ISSN 0947-6539, 1521-3765
Full text not available from this repository. (Request a copy)Abstract
An Ag-I dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | STACKED SUPRAMOLECULAR ASSEMBLIES; COORDINATION POLYMERS; BUILDING-BLOCKS; ANTICANCER ACTIVITY; DONOR LIGANDS; COMPLEXES; FRAMEWORKS; DESIGN; METALLACYCLES; GOLD(I); controlled synthesis; diphosphorus complex; hybrid coordination polymers; organometallic node; preorganized precursor |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:19 |
| Last Modified: | 11 Feb 2019 15:01 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1840 |
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