Marzo, Leyre and Wang, Shun and Koenig, Burkhard (2017) Visible-Light-Mediated Radical Arylation of Anilines with Acceptor-Substituted (Hetero)aryl Halides. ORGANIC LETTERS, 19 (21). pp. 5976-5979. ISSN 1523-7060, 1523-7052
Full text not available from this repository. (Request a copy)Abstract
A visible-light-mediated, catalyst-free, direct (hetero)arylation of anilines with mild reaction conditions has been developed. The formation of a donor-acceptor complex between electron-withdrawing substituted (hetero)aryl halides and anilines allows, under blue LED irradiation, the synthesis of ortho and para (hetero)arylated anilines in moderate to good yields. The reaction has a high functional group tolerance. Spectroscopic studies confirmed the donor-acceptor complex formation between aniline and aryl halide.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ARYLHYDRAZINES; PHOTOCATALYSIS; AZIDATION; PYRROLES; COMPLEX; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:19 |
| Last Modified: | 20 Feb 2019 08:19 |
| URI: | https://pred.uni-regensburg.de/id/eprint/1868 |
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