Scheuermayer, Sabine and Tuna, Floriana and Bodensteiner, Michael and Scheer, Manfred and Layfield, Richard A. (2012) Spin crossover in phosphorus- and arsenic-bridged cyclopentadienyl-manganese(II) dimers. CHEMICAL COMMUNICATIONS, 48 (65). pp. 8087-8089. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
Manganocene reacts with LiE(SiMe3)(2) (E = P or As) to give [(eta(5)-Cp)Mn{mu-E(SiMe3)(2)}](2), where E = P (1) or As (2). The temperature dependence of the magnetic susceptibility in 1 and 2 is due to antiferromagnetic exchange and to spin-crossover (SCO). Compound 2 shows two-step SCO with hysteresis, involving high-spin (S = 5/2) and intermediate-spin S = (3/2) Mn(II).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | IRON(II) COMPLEXES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; LOW-COORDINATE; TRANSITION; COBALT(II); MANGANESE(II); MN; PHOSPHIDO; LIGANDS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 26 May 2020 05:11 |
| Last Modified: | 26 May 2020 05:11 |
| URI: | https://pred.uni-regensburg.de/id/eprint/19460 |
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