Heinl, Sebastian and Balazs, Gabor and Bodensteiner, Michael and Scheer, Manfred (2016) Synthesis and characterization of manganese triple-decker complexes. DALTON TRANSACTIONS, 45 (5). pp. 1962-1966. ISSN 1477-9226, 1477-9234
Full text not available from this repository. (Request a copy)Abstract
The use of the highly sterically demanding Cp-BIG ligand (Cp-BIG = C-5(4-nBuC(6)H(4))(5)) and white phosphorus (P-4) enables the synthesis of new P-rich derivatives of the rare P-n ligand complexes of manganese. The obtained complexes, [{(CpMn)-Mn-BIG}(2)(mu,eta(5:5)-P-5)] (2) and [{(CpMn)-Mn-BIG}(2)(mu,eta(2:2)-P-2)(2)] (3), exhibit the highest number of P atoms in this class of manganese compounds identified by X-ray structure analyses. The EPR spectrum of the 29 VE triple-decker complex 2 shows one unpaired electron coupling with two 5/2 spin Mn nuclei.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE; P-4 ACTIVATION; PHOSPHORUS; LIGAND; CYCLO-P5; INTACT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2019 12:36 |
| Last Modified: | 06 Mar 2019 08:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2175 |
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