Rackl, Daniel and Kreitmeier, Peter and Reiser, Oliver (2016) Synthesis of a polyisobutylene-tagged fac-Ir(ppy)(3) complex and its application as recyclable visible-light photocatalyst in a continuous flow process. GREEN CHEMISTRY, 18 (1). pp. 214-219. ISSN 1463-9262, 1463-9270
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The facile synthesis and application of a polyisobutylene-polymer-tagged, iridium(III) photocatalyst is described. The catalytic performance of this complex remains consistently high, while the installed tether allows for its convenient separation from reaction products through a thermomorphic solvent system. Excellent recycling properties were observed both in batch and in flow reactions, and especially in the latter the continuous, automatic recovery and reuse of the catalyst either from a mono-or a biphasic reaction solution is realised, making this approach attractive for large-scale applications.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSFER RADICAL-ADDITION; PHOTOREDOX CATALYSIS; ORGANIC-SYNTHESIS; ELECTRON-TRANSFER; FACILE SYNTHESIS; C-C; ALKENES; HALIDES; COPPER; BOND; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2019 12:36 |
| Last Modified: | 11 Mar 2019 09:20 |
| URI: | https://pred.uni-regensburg.de/id/eprint/2245 |
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